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http://localhost:8080/xmlui/handle/123456789/3706| Title: | Preparation, characterization and theoretical study of metal complexes derived from N5 acyclic ligand |
| Authors: | Al-jibouri, Mahmoud Najim AL-Obaidi, Omar Hamad Shehab |
| Keywords: | Preparation, Characterization, Theoretical Study, Metal Complexes, Acyclic Ligand |
| Issue Date: | 2013 |
| Publisher: | American Journal of Applied Chemistry |
| Abstract: | The complexes of a new pentadentate acyclic ligand derived from 1,2-diamino benzen and 2,6- diacetylpyridine ,with vanadium(IV), Mn(II) and Fe(III )have been synthesized and characterized on the bases of their elemental analysis, GS mass for ligand, conductivity, magnetic moments in addition to spectral data of IR and UV-Visible Spectra. Metal to ligand ratio in all complexes has been found to be (1:1). The polydentate ligand behaves as N5 system upon linkage with Fe(III) and Mn(II) ions. All the complexes have been assigned as octahedral geometries of general formula [MnL]Cl, [FeLCl]Cl2 and [VOL]SO. A theoretical treatment of the formation of complexes in the gas phase was studied; this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations. |
| URI: | http://localhost:8080/xmlui/handle/123456789/3706 |
| ISSN: | 2330-8745. |
| Appears in Collections: | قسم الكيمياء |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Preparation, characterization and theoretical study of.pdf | 295.76 kB | Adobe PDF | View/Open |
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