Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/6880
Title: Synthesis of 3,6-Diazahomoadamantane
Authors: A. I. Kuznetsov, I. M. Senan
A. Kh. Shukkur, I. A. Azzheurova
T. M. Serova
Issue Date: 2012
Publisher: RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
Abstract: Condensation of 1-phenylsulfanylpropan-2-one with 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane gave 1-phenylsulfanyl-3,6-diazahomoadamantan-9-one which was reduced to 1-phenylsulfanyl-3,6-diazahomo adamantane, and the latter was subjected to desulfurization over Raney nickel to obtain previously unknown 3,6-diazahomoadamantane. Heating of 9-phenyl-3,6-diazahomoadamantan-9-ols with Raney nickel resulted in reduction of the hydroxy group with formation of 9-phenyl-3,6-diazahomoadamantanes.
URI: http://localhost:8080/xmlui/handle/123456789/6880
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