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Title: | Synthesis of 3,6-Diazahomoadamantane |
Authors: | A. I. Kuznetsov, I. M. Senan A. Kh. Shukkur, I. A. Azzheurova T. M. Serova |
Issue Date: | 2012 |
Publisher: | RUSSIAN JOURNAL OF ORGANIC CHEMISTRY |
Abstract: | Condensation of 1-phenylsulfanylpropan-2-one with 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane gave 1-phenylsulfanyl-3,6-diazahomoadamantan-9-one which was reduced to 1-phenylsulfanyl-3,6-diazahomo adamantane, and the latter was subjected to desulfurization over Raney nickel to obtain previously unknown 3,6-diazahomoadamantane. Heating of 9-phenyl-3,6-diazahomoadamantan-9-ols with Raney nickel resulted in reduction of the hydroxy group with formation of 9-phenyl-3,6-diazahomoadamantanes. |
URI: | http://localhost:8080/xmlui/handle/123456789/6880 |
Appears in Collections: | قسم الكيمياء |
Files in This Item:
File | Description | Size | Format | |
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د.احمد حمد شكر3.pdf | 180.71 kB | Adobe PDF | View/Open |
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